Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 6, Pages 818-821Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2011.02.017
Keywords
Coordination polymer; Bis(chelating) bridging ligand; Bowl-shaped voids
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Funding
- National Natural Science Foundation of China [20771040, 21003053]
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Two new coordination polymers, {[Mn-3(BIC)(3)(H2O)(4)]center dot C2H5OH center dot H2O}(n) (1) and {[Mn-3(BIC)(3)(H2O)(4)]center dot C3H6O center dot H2O}(n) (2, C3H6O = acetone), were obtained under hydrothermal conditions. Both of them are 2D networks containing bowl-shaped voids, which are occupied by EtOH and Me2CO molecules, respectively. Furthermore, the single 2D layer is chiral, which is assembled by the bis(chelating) bridging ligands and two kinds of Mn(II) coordination units. (C) 2011 Elsevier B.V. All rights reserved.
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