Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 11, Pages 1846-1849Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2011.08.026
Keywords
Supramolecular assembly; Keggin cluster; Basketlike cage; Electrochemical property; Electrocatalysis behavior
Categories
Funding
- National Natural Science Foundation of China [20671026, 20971032]
- Special Foundation of Harbin [2009RFXXG202]
- Education Office of Heilongjiang Province [11551122]
- College of Heilongjiang Province [2009td04]
- Harbin Normal University [KJTD200902]
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A novel supramolecular compound based on the Keggin cluster and basketlike cage (C10H10N2)(12)((PMo12O40)-O-VI)(2)(Sr subset of (P6Mo3Mo15O73)-Mo-V-O-VI)(2)center dot 9H(2)O (1), has been hydrothermally synthesized and characterized by elemental analysis, IR. TG, XPS, UV and single-crystal X-ray diffraction. In compound 1, the basketlike polyanion uses its surface oxygen atoms to attract nine basket cages and five Keggin clusters via strong supramolecular interactions. Meanwhile, each of Keggin cluster is surrounded by its neighboring five basket cages in the same mode to form a 3D supramolecular framework with chambers, and 4,4'-bipy organic molecules are located in the chambers to stabilize the whole structure. The electrochemical and electrocatalysis behavioral 1-CPE have been studied in detail. (C) 2011 Elsevier B.V. All rights reserved.
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