Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 14, Issue 1, Pages 194-196Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2010.10.020
Keywords
Supramolecular chemistry; Magnetic property; Organic free radical; Lanthanum; Bipyridine
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Funding
- MEXT, Japan [21110513, 22350059]
- Grants-in-Aid for Scientific Research [22350059] Funding Source: KAKEN
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The title compound was proposed as a paramagnetic host, and its chelation ability was confirmed by inclusion of a size-matching lanthanum(III) ion. The anti-configuration of the free ligand was changed to the syn configuration in the complex. The antiferromagnetic coupling was enhanced after complexation. In addition to the change of the intramolecular magnetic coupling, a superexchange mechanism is also assumed across the nitroxide-lanthanum(III)-nitroxide structure. (C) 2010 Elsevier B.V. All rights reserved.
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