Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 13, Issue 3, Pages 334-337Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2009.12.007
Keywords
Bioinorganic chemistry; Heterodinuclear; Dinuclear; Purple acid phosphatase; Model complexes; Transesterification; HPNP; Iron; Zinc
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Funding
- Swedish Science Research Council
- Academy of Finland
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The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved
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