Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 13, Issue 10, Pages 1144-1147Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2010.06.030
Keywords
Crystal structure; Porphyrin; Phthalocyanine; Self-assembly; Rare earth
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Funding
- Natural Science Foundation of China [20931001, 20801031]
- Ministry of Education of China
- Independent Innovation Foundation of USTB and SDU
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A mixed phthalocyaninato and porphyrinato triple-decker complex [Eu-2(Pc)(2)(TCIPP)] was synthesized and characterized by elemental analysis, FT-IR, UV, and X-ray structure determination. Its self-assembling properties in mixed chloroform/methanol solution were investigated by TEM, SEM and XRD techniques. Investigation revealing the availability of the single crystal, together with the molecular structure, renders it possible to investigate the formation mechanism as well as the molecular packing conformation of self-assembled nanostructures fabricated from this complex in a more confirmed manner. (C) 2010 Elsevier B.V. All rights reserved.
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