Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 13, Issue 11, Pages 1227-1230Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2010.06.011
Keywords
Coordination polymer; Zinc(II); Template; Macrometallocycle; Luminescence
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Funding
- NNSF of China [20703008, 20701006]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0714]
- PhD Station Foundation of Ministry of Education for New Teachers [20070200014/20070200015]
- Postdoctoral Foundation of Northeast Normal University
- Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education
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A new Zn(II) coordination polymer, [Zn-3(pzdc)(4)]center dot en (1) (H(2)pzdc = pyrazine-2,3-dicarboxylic acid, en = ethylenediamine), has been prepared under hydrothermal condition. X-ray diffraction analysis shows that 1 has a 3D structure with micropores (calcd. 4.074 x 6.444 angstrom(2)) along the [100] direction filled with en guest molecules. Notably, the pzdc groups connect Zn(II) cations to form a macrometallocycle as the subunit, which is further connected to generate the final framework. Additionally, the luminescent property of compound 1 has been investigated in detail. (C) 2010 Elsevier B.V. All rights reserved.
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