Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 12, Issue 8, Pages 716-719Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2009.05.026
Keywords
Dendrimers; Rhodium complexes; Poly(propyleneimine); Iminophosphine; P,N-heterobidentate
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Funding
- Anglo Platinum Corporation
- University of Cape Town
- National Research Foundation (NRF) of South Africa
- NRF-DST Centre of Excellence in Catalysis
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First (G1)- and second-generation (G2) poly(propyleneimine) (PPI) dendrimers were reacted with 2-(diphenylphosphino)benzaldehyde, to form iminophosphine-functionalised dendritic ligands (1, 2). The reaction of the dimeric precursor [RhCl(CO)(2)](2) with the heterobidentate dendritic ligands 1, 2 gave the corresponding rhodium(l) complexes (3,4). (C) 2009 Elsevier B.V. All rights reserved.
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