4.7 Article

Two 2-D homometallic and heterometallic Schiff-base complexes bridged by dicyanamide

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 12, Issue 3, Pages 255-258

Publisher

ELSEVIER
DOI: 10.1016/j.inoche.2008.12.024

Keywords

Schiff-base compound; Homometallic and heterometallic complexes; Crystal structure; Thermal analysis; Fluorescent property

Funding

  1. NSFC of China [20601021]
  2. Educational Department Project of Zhejiang Province [20060375]

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Two Schiff-base complexes composed of homometallic and heterometallic dinuclear units, [Zn-2(salpn)](2+) and [CuCd(salpn)](2+), have been prepared and characterized. The dinuclear second building units are connected by dicyanamide (dca) ligands, forming 2-D layer structure. Zinc(II) complex displayed structure-related photoluminescence properties in the solid state. (C) 2009 Elsevier B.V. All rights reserved.

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