Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 12, Issue 2, Pages 166-168Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2008.12.005
Keywords
Coordination polymer; Microporous material; Crystal structure; Desorption/adsorption
Categories
Funding
- Foundation of the Major State Basic Research Development Program [2006CB806104]
- National Found for Fostering Talents of Basic Science [J0630425]
- Foundation of Nanjing University [020522420111]
- State Key Laboratory of Coordination Chemistry
- Center of Analysis and Determining of Nanjing University
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Two stable supramolecular microporous polymers with double-layer structures, [Co(AIP) (BPY)(0.5) center dot H2O](n)center dot 2nH(2)O (1) and [Ni(AIP)(BPY)(0.5) center dot H2O](n) center dot 2nH(2)O (2), were constructed from AIP (5-aminoisophthalate) and BPY (4,4'-bipyridine) under hydrothermal conditions. Both of them exhibit rarely reported (3,4)-connected (6(3))(6(5)8) topology and interesting water-induced reversible transformation properties that are confirmed by PXRD studies. (c) 2008 Elsevier B.V. All rights reserved.
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