Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 11, Pages 1327-1329Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2008.08.011
Keywords
Thiogallate; Lanthanide complex; Solvothermal synthesis; Crystal structure
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Funding
- National Natural Science Foundation [20371033]
- Natural Science Foundation of the Education Committee of Guangxi Province
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The title compound, [Dy-2(en)(6)(mu(2)-OH)(2)]Ga4S8 (en=ethylenediamine), contains I D infinite sinusoidal [GaS2-](n). anions and hydroxy bridged dinuclear dysprosium complex cations' Two bridging hydroxy ions connect two inversion-related Dy3+ ions to form a centrosymmetric dimer, in which a Dy2O2 rhomboidal core is formed. The title compound is the only example of the thiogallates with lanthanide-containing counter cation. (C) 2008 Elsevier B.V. All rights reserved.
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