Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 10, Pages 1221-1223Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2008.07.014
Keywords
2,2 ',4,4 '-Biphenyltetracarboxylic acid; Zn-2(OH)(2) diamond-core chains; Crystal structure; Hydrothermal synthesis
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Funding
- Development Foundation of Shanghai Municipal Education Committee, China [06AZ098]
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Reaction of 2,2',4,4'-biphenyltetracarboxylic acid (2,4-H(4)bptc), Zn(NO3)(2) center dot 6H(2)O in the presence of NaOH hydrothermally at 180 degrees C affords the first 2,4-H(4)bptc complex [Zn-3(mu(3)-OH)(2)(2,4-bptc)(n) center dot 2nH(2)O (1). Crystal structure indicates that 1 is Zn-2(OH)(2) diamond-core chains linked through 2,2',4,4'-biphenyltetracarboxylate. I was characterized by TG, IR and fluorescence spectra. 1 is the first example of 2,4-H(4)bptc complex and also first neat Zn-2(OH)(2) diamond-core chains. (C) 2008 Elsevier B.V. All rights reserved.
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