Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 10, Pages 1187-1189Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2008.07.006
Keywords
2-hydroxy-N-((pyridin-2-yl) methyl); benzamide; Sandglass; Terbium; OLEO
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Funding
- Postdoctoral Foundation of China [2007-31000-4109337]
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The synthesis, crystal structure and photophysical properties of [Tb{Tb-4(hpmba)(8)(mu(3)-OH)(4)(mu(4)-OH)}(2)OH] (hpmba = 2-hydroxy-N-((pyridin-2-yl)methyl)benzamide) was presented. The crystal structure exhibits a novel sandglass-like nonanuclear structure. The complex is strongly emissive with the lifetime about 1.02 ms at 546 nm in CH3CN at 298 K. The ITO/PVK/complex/Al OLED with the compound as a light-emitting material has also been fabricated: it has a maximum electroluminescence intensity when the driving voltages were increased to 11 V. (C) 2008 Elsevier B.V. All rights reserved.
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