Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 12, Pages 1462-1465Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2008.10.004
Keywords
N-Heterocyclic carbenes; Palladium-carbene complexes; Crystal structure; Suzuki-Miyaura cross-coupling reaction; Palladium catalyst
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Funding
- Technological and Scientific Research Council of Turkey TUBiTAK-CNRS [TBAG-U/181 (106T716)]
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A palladium(II) complex, bis[1,3-bis-(2,4,6-trimethylbenzyl)benzimidazol-2 -ylidene]palladium(II) chloride, Pd(NHC), bearing N-heterocyclic carbenes has been synthesized and characterized by elemental analysis, IR spectroscopy and H-1 and C-13 NMR spectroscopy. Crystal structure details of Pd(NHC) are also presented. The palladium centre in the complex lies on a crystallographic inversion centre and occupies a square-planar environment. with both chloride and N-heterocyclic carbene ligands adopting a trans arrangement with Cl-Pd-Cl and C-Pd-C angles are precisely 180 degrees. The palladium-carbene complex was tested as a catalyst in the Suzuki-Miyaura cross-coupling reaction. (c) 2008 Elsevier B.V. All rights reserved.
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