4.7 Article

Synthesis, structure and near-infrared (NIR) luminescence of three solvent-induced pseudo-polymorphic complexes from a bimetallic Zn-Nd Schiff-base molecular unit

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 11, Pages 1316-1319

Publisher

ELSEVIER
DOI: 10.1016/j.inoche.2008.08.012

Keywords

Solvent-induced pseudo-polymorphism; Bimetallic Zn-Nd Schiff-base complex; Intermolecular pi-pi interaction; NIR luminescence

Funding

  1. Hong Kong Grants Council
  2. Provincial Natural Foundation [2007BO3]
  3. Education Committee Foundation of Shaanxi Province [07JK391]
  4. Northwest University in PR China [07YJC11]

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Three solvent-induced pseudo-polymorphic bimetallic Zn-Nd complexes [ZnNdL(OAc)(NO3)(2)(DMF)] solvate (solvate: MeCN (1), THF (2), EtOH (3): H2L = N,N'-bis(3-methoxy-salicylidene)phenylene-1,2-diamine) were obtained, and their solid NIR luminescence related to the packing structure from the intermolecular pi-pi interactions was discussed. (C) 2008 Elsevier B.V. All rights reserved.

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