Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 7, Pages 717-719Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2008.03.016
Keywords
metallamacrocycle; manganese complex; crystal structure; magnetic properties
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A novel cross-net-shaped metal lamacrocycle, [(Mn10Mn4II)-Mn-III(L)(8)(HL)(2)(H2O)(2)(CH3OH)(14)]center dot 8H(2)O center dot 8CH(3)OH (H4L = (Z)-3-(salicylhydrazinocarbonyl) propenoic acid), has been prepared and characterized. The crystal structure contains seven crystallographically unique manganese ions, in which two opening 13-membered metallacrown rings and two strands, Mn-N-N-Mn, are bridged by eight p-maleoyl groups. The high nuclearity of the molecule shows large magnetic moments, with the value of mu(eff) at 300 K is 19.01 VB. (c) 2008 Elsevier B.V. All rights reserved.
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