Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 10, Pages 1170-1173Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2008.06.025
Keywords
N-heterocyclic carbenes (NHCs); Benzimidazole; N-alkylbenzimidazole; N,N '-linked NHC
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Funding
- Kyungpook National University Research Fund, 2007
- National Research Foundation of Korea [과06B1508] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Together with the facile and high yielding formation of N,N'-linked NHC ligand, the complexation of Nmethylbenzimiclazole (1a), N-methylbenzimcliazolium chloride (4a) and N,N,-Iinked NHC ligand, 3,3-dimethyl-1,1-bibenzimidazolium dichloride (2a), with CuO or CuCl2 give a dichloro-bridged binuclear copper(II) species (la), as characterized by IR spectroscopy and X-ray. (C) 2008 Elsevier B.V. All rights reserved.
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