4.7 Article

Delving into the second supramolecular event approach: Aggregation of small metallo-supramolecular units supported by one or two types of non-covalent forces

Journal

INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 9, Pages 995-998

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2008.04.039

Keywords

helicate; palladium(II); hydrogen bond; pi-stacking; supramolecular chemistry

Funding

  1. Spanish MEC [CTQ2006-01339]
  2. Galician DXID [PGI-DIT06PXIB209055PR]
  3. EU COST D31 Action Functional Helicates [D31/0008/04]

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The neutral single-stranded monohelicate [Pd(HL)]center dot 2(CH3CN) (1) aggregates in the solid state to give an infinite 1 D supramolecular chain through either the cooperative action of hydrogen bonding and pi-stacking interactions or by aromatic pi-stacking alone. (C) 2008 Elsevier B.V. All rights reserved.

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