Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 11, Issue 10, Pages 1250-1252Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2008.07.020
Keywords
Solvothermal synthesis; Microwave-assisted; Crystal structure; MOF; Photoluminescence
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Funding
- National Nature Science Foundation of China
- Natural Science Foundation of the Education Department of Jiangsu Province [06KJD150208]
- Center of Analysis and Determining of Yangzhou University
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A novel three-dimensional (3D) coordination polymer, [Cd(mu(3)-HIDC)(bbi))(0.5)](n) (1) (H3IDC = 4,5-imidazol-edicarboxylic acid, bbi = 1,1'-(1,4-butanediyl)bis(imidazole)), has been synthesized under microwave heating solvothermal conditions and characterized by elemental analysis, IR, TG, and single crystal X-ray diffraction. The crystal structure reveal that compound 1 consists of 2D brickwall-like networks of [Cd(mu(3)-HIDC)](n), which are further linked through mu(2)-bbi to generate a 3D structure. Compound 1 is stable up to 330 degrees C and displays strong blue fluorescent emission at room temperature. This work demonstrates that microwave-assisted solvothermal synthesis method is an efficient and fast way to prepare metal coordination polymers. (C) 2008 Elsevier B.V. All rights reserved
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