Journal
INORGANIC CHEMISTRY
Volume 57, Issue 16, Pages 10323-10330Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b01528
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Funding
- National Natural Science Foundations of China [21671040]
- Natural Science Foundations of Fujian Province [2016J05055]
- State Key Laboratory of Structural Chemistry of China [20160020]
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Two unprecedented examples of cluster organic frameworks (TBA)(3)Cu[V6O13(L)(2)](2)center dot 4DEF (2) (TBA)Ag-[V6O13(L)(2)] solvent (3) (TBA = tetrabutylammonium, H3L = tris(hydroxymethyl)-4-picoline, DEF = N,N'-diethylformamide) based on Lindqvist-type polyoxometalate (POM) secondary building units (SBUs) have been constructed successfully. Compounds 2 and 3 are the second cases of cluster organic frameworks based on Lindqvist-type POM cluster SBUs. Furthermore, the cluster organic framework of 2 exhibits efficient electrocatalytic activity and strong durability in oxygen reduction reaction.
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