Journal
INORGANIC CHEMISTRY
Volume 57, Issue 16, Pages 9786-9789Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.8b01630
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21522104, 21431004, 21620102001]
- National Key Basic Research Program of China [2016YFA0203400]
- Key Project of Basic Research of Shanghai [17JC1403100, 18JC1413200]
- Shanghai Eastern Scholar Program
Ask authors/readers for more resources
A chiral porous metal organic framework (MOF) decorated with radicals has been successfully constructed by cocrystallizing achiral (2,2,6,6-tetramethyl-piperidin-1-yl)oxyl (TEMPO)-substituted tricarboxylate and enantiopure VO(salen)-derived dipyridine ligands. The chiral MOF can function as an efficient heterogeneous catalyst for the sequential alcohol oxidation/asymmetric cyanation of aldehyde reactions with enhanced activity and enantioselectivity compared to the homogeneous counterpart.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
