Journal
INORGANIC CHEMISTRY
Volume 53, Issue 22, Pages 11815-11832Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic502231m
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- National Science Foundation [CHE-1265212]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1265212] Funding Source: National Science Foundation
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This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of carbene-stabilized diatomic allotropes, diborenes, gallium octahedra, beryllium borohydride, and a host of related compounds will be presented. Providing a valuable historical perspective, the foundational work concerning the organometallic chemistry of gallium with sterically demanding m-terphenyl ligands from this laboratory will also be discussed.
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