Journal
INORGANIC CHEMISTRY
Volume 53, Issue 7, Pages 3307-3310Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic402107z
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Funding
- Indiana University Office of Vice President for Research
- National Science Foundation/Department of Energy [NSF/CHE-0822838]
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-06CH11357]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1346572] Funding Source: National Science Foundation
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Two different neutral tridentate imine-donor pincer ligands interact with excess MCl2 (M = Co or Cu) to form compounds of the same stoichiometry, (LMCl2)(2)center dot MCl2, where the assembling force is the electron richness of the terminal chlorides on the LMCl2 unit. Finite aggregation occurs for M = Co, but for M = Cu, an infinite polymeric structure is adopted, all because MCl2 is bifunctional, which thus bridges multiple MCl units. The bis-pyrazolylpyridine ligand has two acidic NH protons, and both of these are involved in intramolecular hydrogen bonds. The generality of this Lewis acid aggregation is discussed.
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