Journal
INORGANIC CHEMISTRY
Volume 53, Issue 18, Pages 9463-9465Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic501901n
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- Andlinger Center for Energy and the Environment at Princeton University
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The addition of carbon dioxide to ((PNP)-P-tBu)CoH [(PNP)-P-tBu = 2,6-bis(di-tert-butylphosphinomethyl)pyridine] resulted in rapid insertion into the Co-H bond to form the corresponding kappa(1)-formate complex, which has been structurally characterized. Treatment of ((PNP)-P-tBu)CoH with PhSiH3 resulted in oxidative addition to form trans-((PNP)-P-ttbu)CoH2(SiH2Ph), which undergoes rapid exchange with excess free silane. With 0.5 mol % ((PNP)-P-tBu)CoH, the catalytic hydrosilylation of CO2 with PhSiH3 to a mixture of oligomers containing silyl formate, bis(silyl)acetyl, and silyl ether subunits has been observed.
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