4.7 Article

van der Waals Radii of Noble Gases

Journal

INORGANIC CHEMISTRY
Volume 53, Issue 17, Pages 9260-9266

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic501364h

Keywords

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Funding

  1. Dr. Barbara Mez-Starck Foundation
  2. Spanish Ministerio de Economia y Competitividad [CTQ2011-23862-C02-02]
  3. Generalitat de Catalunya [2009SGR-1459]

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Consistent van der Waals radii are deduced for Ne-Xe, based on the noble gas oxygen intermolecular distances found in gas phase structures. The set of radii proposed is shown to provide van der Waals distances for a wide variety of noble gas. element atom pairs that represent properly the distribution of distances both in the gas phase and in the solid state. Moreover, these radii show a smooth periodic trend down the group which is parallel to that shown by the halogens.

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