Journal
INORGANIC CHEMISTRY
Volume 53, Issue 19, Pages 10009-10011Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic501195y
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Funding
- Polish National Science Centre [2012/07/N/ST5/02213]
- MICINN (Spain) [CTQ2010-15364]
- Generalitat Valenciana (Spain) [PROMETEO/2009/108, ISIC/2012/002]
- Universitat de Valencia
- European Social Fund
- MICINN Ramon y Cajal Program
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The six-coordinate cobalt(II) complex of formula [Co(tppz)(2)](tcm)(2) exhibits a thermally induced spin-crossover behavior from a high spin (S = 3/2) at higher temperatures to a low spin (S = 1/2) at lower temperatures, with the low-spin phase being achieved at T <= 200 K
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