Journal
INORGANIC CHEMISTRY
Volume 53, Issue 2, Pages 685-687Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic402598p
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Funding
- National Natural Science Foundation [21371155, 91022013]
- Research Fund for the Doctoral Program of Higher Education of China [20124101110002]
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The conversion from a [2 + 2] nested double-helical column, {[Mn-2(ptptp)(suc) (H2O)(2)]center dot 1.5H(2)O}(n) (1), to a cationic spiral staircase, {[Mn-2(ptptp)-(suc)(0.5)(H2O)(3)]center dot Br center dot 0.5H(2)O}(n) (2), has been achieved through ionic liquid anion stimulations under solvothermal conditions. The conversion does not change the antiferromagnetic interactions.
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