4.7 Article

A New FeMo Complex as a Model of Heterobimetallic Assemblies in Natural Systems: Mossbauer and Density Functional Theory Investigations

Journal

INORGANIC CHEMISTRY
Volume 53, Issue 21, Pages 11345-11347

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic501875q

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Funding

  1. Centre National de la Recherche Scientifique (CNRS)
  2. Universite de Bretagne Occidentale (UBO)
  3. Universite Joseph Fourier
  4. Grenoble-1
  5. Agence Nationale de la Recherche [ANR-11-LABX-0003-01]
  6. University of Milano-Bicocca

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The design of the new FeMo heterobimetallic species [FeMo(CO)(5)(kappa(2)-dppe)(mu-pdt)] is reported. Mossbauer spectroscopy and density functional theory calculations give deep insight into the electronic and structural properties of this compound.

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