Journal
INORGANIC CHEMISTRY
Volume 53, Issue 14, Pages 7288-7293Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic500629y
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Funding
- Basic Science Research Program through the National Research Foundation of Korea [2012R1A1A2004333]
- National Research Foundation of Korea [2012R1A1A2004333] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A series of new Ti(IV)-oxo clusters supported by carboxylate ligands are synthesized by solvothermal reactions, and their crystal structures and gas sorption properties are studied in detail. Depending on the reaction medium, two types of Ti6O6 clusters are formed with benzoate-derived ligands whose 2- or 4-position is substituted by a hydrophobic moiety. The molecular packing structures of these Ti clusters are found stable against water- and heat-treatments. Gas sorption studies reveal that a dense-packed Ti-carboxylate cluster can adsorb almost the same number of CO2 molecules as the one with considerable intermolecular voids in the packing structure. The effect of benzoate substituents on the gas sorption behavior is discussed.
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