Journal
INORGANIC CHEMISTRY
Volume 53, Issue 3, Pages 1679-1689Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic4028332
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Centre for Self-Assembled Chemical Structure (CSACS)
- MIUR
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The synthesis and characterization of a novel family of [Ru-II(bpy)(2)(N-N)](PF6)(2) (bpy = 2,2'-bypyridine) complexes are reported, where N-N = pyridine/pyrimidine/pyrazine functionalized in different positions with the electron-donating bicyclic hexahydropyrimidopyrimidine (hpp) unit. A series of bidentate ligands 1a-5a were synthesized in good to high yields (55-96%). The corresponding complexes 1b, 2b, and 5b were prepared in n-butanol, while complexes 3b and 4b were prepared in a mixture of n-butanol and water (1/1, v/v) in modest to good yields (23-76%). Both ligand and complex structures were fully characterized by a variety of techniques, including X-ray crystallography. In cyclic voltammetric studies, all the complexes exhibit a Ru-III/II couple, which is similar to 500 mV less positive than the Ru-III/II couple in Ru(bpy)(3)(2+). The (MLCT)-M-1 and (MLCT)-M-3 states of all of the complexes (530-560 nm/732-745 nm) are shifted bathochromically in comparison to those of Ru(bpy)(3)(2+) (450 nm/620 nm). These values are in good agreement with DFT and TD-DFT calculations.
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