Journal
INORGANIC CHEMISTRY
Volume 53, Issue 10, Pages 5179-5188Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic500298u
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Funding
- German Science Foundation (DFG) [KO 2288/20-1, KO 2288/4-1, KO 2288/3-1, KO 2288/3-2]
- CMST COST Action [CM1203]
- Jacobs University
- DAAD
- Higher Education Commission of Pakistan
- Institute of Nanotechnology (INT)-Karlsruhe Institute of Technology (KIT)
- DFG Center for Functional Nanostructures
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Interaction of the trilacunary Keggin polyanions [A-alpha-XW9O34](10-) (X = Si-IV, Ge-IV) with Co-II and phosphate ions in aqueous, basic media and under mild heating leads to the formation of the tetrameric, Co-16-containing heteropolytungstates [{Co-4(OH)(3)PO4}(4)(A-alpha-XW9O34)(4)](32-) (X = Si-IV, Ge-IV). Both polyanions were characterized in the solid state by single-crystal X-ray diffraction, IR spectroscopy, and thermogravirnetric and elemental analyses. Furthermore, the electrochemical and magnetic properties of these isostructural polyanions were investigated.
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