Journal
INORGANIC CHEMISTRY
Volume 53, Issue 19, Pages 10024-10026Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic501492c
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Funding
- National Science Foundation of China [21201077, 21171065, 21304092]
- Fundamental Research Funds for the Central Universities [201103099]
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Indium metal-organic frameworks (MOFs) were first used as recyclable heterogeneous Lewis acid catalysts for the synthesis of amino acid derivatives with excellent conversion yields. Moreover, exposed ether groups (Lewis basic sites) on the pore walls of In-MOF 2 could activate trimethylsilyl cyanide, forming hypervalent silicate intermediates, as proven by Si-29 NMR.
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