Journal
INORGANIC CHEMISTRY
Volume 54, Issue 1, Pages 280-292Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic502430e
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Funding
- Italian MIUR (PRIN Project) [2010N3T9M4]
- Italian MIUR (FIRB Project) [RBAP11C58Y]
- University of Trieste [FRA2009, FRA2012]
- Fondazione Beneficentia Stiftung
- Deutsche Forschungsgemeinschaft [KA 3491/2-1]
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A new triad system featuring one zinc porphyrin and one fullerene moieties attached to a central redox-active Re(I) connector was obtained in remarkable yield by cleverly exploiting a facile two-step synthesis. Detailed description and discussion on the characterization of this multicomponent system and of its parent free-base analogue are presented, along with a kinetic study of the stepwise electron-transfer processes occurring upon visible excitation.
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