Journal
INORGANIC CHEMISTRY
Volume 53, Issue 7, Pages 3832-3838Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic5001683
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- CINECA
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The 1:1 molar reaction of WCl6 with tribenzylamine (tba), in dichloromethane, selectively afforded the iminium salt [(PhCH2)(2)N=CHPh][WCl6], 1, and the ammonium one [tbaH][WCl6], 2, in equimolar amounts. The products were fully characterized by means of spectroscopic methods, analytical methods, and X-ray diffractometry. Density functional theory calculations were carried out with the aim of comprehending the mechanistic aspects.
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