Journal
INORGANIC CHEMISTRY
Volume 53, Issue 3, Pages 1263-1265Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic402816a
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Funding
- FRS-FNRS [FRFC 2.4508.08, 2.4537.12]
- RNASR
- CNCS-UEFISCDI [PN-II-RU-TE-2011-3-0307]
- Romanian Academy
- WBI
- COST action [MP1202]
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A mononuclear iron(II) neutral complex (1) is screened for sensing abilities for a wide spectrum of chemicals and to evaluate the response function toward physical perturbation like temperature and mechanical stress. Interestingly, 1 precisely detects methanol among an alcohol series. The sensing process is visually detectable, fatigue-resistant, highly selective, and reusable. The sensing ability is attributed to molecular sieving and subsequent spin-state change of iron centers, after a crystal-to-crystal transformation.
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