4.7 Article

Zn(II)-Benzotriazolate Clusters Based Amide Functionalized Porous Coordination Polymers with High CO2 Adsorption Selectivity

Journal

INORGANIC CHEMISTRY
Volume 53, Issue 17, Pages 8842-8844

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic500788z

Keywords

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Funding

  1. 973 Program of China [2012CB821700, 2014CB845600]
  2. National Science Foundation of China [21031002, 21290171, 21202088]
  3. MOE Innovation Team of China [IRT13022]

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Two new porous coordination polymers (PCPs) based on different nanosized C-3 symmetry ligands and Zn(II)-benzotriazolate clusters have been synthesized solvothermally. Both of the desolvated complexes show selective uptake of CO2 over CH4 and N-2 at ambient temperature.

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