Journal
INORGANIC CHEMISTRY
Volume 53, Issue 11, Pages 5414-5416Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic500558j
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Funding
- National Science Foundation (NSF) [CHE-0748607]
- NSF award [CHE-0821487]
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We report the synthesis, structure, and reactivity of [Fe(T1Et4iPrIP)(OTf)(2)] [1; T1Et4iPrIP = tris(1-ethyl-4-isopropylimidazolyl)phosphine]. Compound 1 reacts reversibly with nitric oxide to afford [Fe-(T1Et4iPrIP)(NO)(THF)(OTf)](OTf) (2), which is the first example of a 6-coordinate {FeNO}(7) S = 3/2 complex containing a linear Fe-N-O group. 2 exhibits the highest nu(NO) for compounds in this class. Density functional theory studies reveal an enhanced degree of beta-electron transfer from pi*(NO) to the Fe d orbitals accounting for the large stretching frequency.
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