4.7 Article

Enantioselective Inclusion of Alcohols by Solvent-Controlled Assembled Flexible Metal-Organic Frameworks

Journal

INORGANIC CHEMISTRY
Volume 53, Issue 10, Pages 4794-4796

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic500436g

Keywords

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Funding

  1. 973 Key Program of the MOST [2010CB933501, 2012CB821705]
  2. Chinese Academy of Sciences [KJCX2-YW-319, KJCX2-EW-H01]
  3. National Natural Science Foundation of China [21373221, 21221001, 91022008, 91122027, 51172232]
  4. Natural Science Foundation of Fujian Province [2011HZ0001-1, 2012J06006, 2006L2005, 2014J05026]

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Through judicious choice of the ligands and patient regulation of the solvent conditions, three unique chiral coordination polymeric isomers have been synthesized. Their structures, gas adsorption, and structural interconversion have been studied. One of the isomers displays dynamic behavior, and its use in the enantioselective separation of chiral alcohols has also been reported.

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