Journal
INORGANIC CHEMISTRY
Volume 53, Issue 16, Pages 8662-8671Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic501265k
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Funding
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Canada Foundation for Innovation (CFI)
- Alberta Innovates Technology Futures
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This article outlines our attempts to stabilize the Group 14 element dihydrides, GeH2 and SnH2, using commonly employed phosphine and pyridine donors; in each case, elemental Ge and Sn extrusion was noted. However, when these phosphorus and nitrogen donors were replaced with the ylidic Wittig ligand Ph3P=CMe2, stable inorganic methylene complexes (EH2) were obtained, demonstrating the utility of this under-explored ligand class in advancing main group element coordination chemistry.
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