Journal
INORGANIC CHEMISTRY
Volume 53, Issue 15, Pages 7941-7950Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic500714h
Keywords
-
Categories
Funding
- International Fulbright Science & Technology fellowship
- UC Fees program
- NSF IGERT program [DGE-1144885]
Ask authors/readers for more resources
Bis-corroles have been prepared through a convergent synthesis using a copper-catalyzed azide-alkyne cycloaddition. Synthesis of the final homo- and heterobimetallic complexes has been achieved in three to four steps from commercially available materials in good overall yield. Meso-substituted corroles functionalized with a single azido or propargyl group were used as key starting materials. (C6F5)(2)(p-O(CH2CCH)Ph)corroleH(3) (I) and ((C6F5)2(m-CH2N3)Ph)corroleH(3) (3) were metalated with copper or iron and attached by Huisgen azide-alkyne cycloaddition (click reaction) first to small substrates and then to each other, demonstrating a convergent synthesis of bimetallic bis-corrole molecules.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available