4.7 Article

Nonporous Titanium-Oxo Molecular Clusters That Reversibly and Selectively Adsorb Carbon Dioxide

Journal

INORGANIC CHEMISTRY
Volume 52, Issue 17, Pages 9705-9707

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic401122u

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Funding

  1. Basic Science Research Program through the National Research Foundation of Korea
  2. Ministry of Education, Science and Technology [2011-0027419, 2012R1A1A2004333]
  3. National Research Foundation of Korea [2009-0087194, 2012R1A1A2004333] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Nonporous titanium(IV) clusters supported by carboxylate ligands show selective sorption of carbon dioxide even in the amorphous phase. A ring type Ti-8 cluster with a permanent inner pore also adsorbs gases, but not selectively.

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