4.7 Article

Synthesis, Structure, and H2/CO2 Adsorption in a Three-Dimensional 4-Connected Triorganotin Coordination Polymer with a sqc Topology

Journal

INORGANIC CHEMISTRY
Volume 52, Issue 7, Pages 3579-3581

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic302528b

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Funding

  1. Department of Science and Technology, India
  2. Council of Scientific and Industrial Research, India
  3. Department of Science and Technology
  4. UGC, India
  5. CSIR [NWP0022, NWP0021]
  6. DST [SR/S1/IC-22/2009]

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A 4-connected triorganotin 3D coordination polymer in a sqc topology has been shown to possess 1D microchannels along its crystallographic a axis. This main-group-element-containing framework structure shows selective gas adsorption, preferring CO2 and H-2 over N-2.

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