4.7 Article

In Situ Construction of a Coordination Zirconocene Tetrahedron

Journal

INORGANIC CHEMISTRY
Volume 52, Issue 24, Pages 13815-13817

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic402428m

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Funding

  1. NSFC [21271172, 21131006]
  2. Chinese Academy of Sciences
  3. NSF of Fujian Province [2012J01058]

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The current study describes the first in situ synthesis and characterization of a new family of cationic coordination tetrahedra of both the V4F4 and V4E6 type, which are constructed by a new building block based on a trinuclear zirconocene moiety and the dicarboxylate or tricarboxylate anions.

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