4.7 Article

A Straight Forward Route for the Development of Metal-Organic Frameworks Functionalized with Aromatic -OH Groups: Synthesis, Characterization, and Gas (N2, Ar, H2, CO2, CH4, NH3) Sorption Properties

Journal

INORGANIC CHEMISTRY
Volume 52, Issue 2, Pages 855-862

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ic302010e

Keywords

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Funding

  1. EU (European Social Fund - ESF)
  2. Greek national funds through the Operational Program Education and Lifelong Learning of the National Strategic Reference Framework (NSRF) - Research Funding Programs: THALES and HERACLEITUS II
  3. EU (European Regional Development Fund)
  4. Greek Ministry of Education/EYDE-ETAK [09SigmaYN-42-831]
  5. UoC
  6. NSF/Department of Energy (DOE) [CHE-0535644]
  7. DOE, Office of Basic Energy Sciences [DE-AC02-06CH11357]
  8. Division Of Chemistry
  9. Direct For Mathematical & Physical Scien [0822838] Funding Source: National Science Foundation

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A facile and general methodology for the development of metal-organic frameworks (MOFs) functionalized with pendant, aromatic hydroxyl (-OH) groups is presented. Extensive gas-sorption studies in representative and important MOFs functionalized with free aromatic -OH groups such as the IRMOF-8 and DUT-6 (or MOF-205), denoted here as 1 and 2, revealed a high CO2/CH4 selectivity for 1 (13.6 at 273 K and 1 bar) and a high NH3 uptake of 16.4 mol kg(-1) at 298 K and 1 bar for 2.

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