Journal
INORGANIC CHEMISTRY
Volume 52, Issue 6, Pages 2796-2798Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic302827s
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Funding
- National Science Foundation (NSF) [CHE-0911543, DMR-0832760, CHE-0802907]
- NSF [CHE-8813550, CHE-9629688, CHE-0342998]
- National Institutes of Health [1S10RR004981-01]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0802907, 911543] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [832760] Funding Source: National Science Foundation
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A modular synthetic method has been developed for the preparation of Ru polypyridyl complexes bearing a terminal alkyne. This method proceeds through a readily accessible intermediate with a silyl-protected alkyne and allows access to a variety of five- and six-coordinate Ru complexes. These complexes can be easily attached to azide-functionalized electrode surfaces with only slight perturbation of the redox properties of the parent complex.
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