Journal
INORGANIC CHEMISTRY
Volume 52, Issue 9, Pages 4777-4779Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic4005517
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- MICINN (Spain) [CTQ2010-15364]
- University of Valencia [UV-INV-AE11-38904]
- Generalitat Valenciana (Spain) [PROMETEO/2009/108, GV/2012/051, ISIC/2012/002]
- MICINN
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The reaction of N-(2,6-dimethylphenyl)oxamic acid with dysprosium(III) ions in a controlled basic media afforded the first example of a mononuclear lanthanide oxamate complex exhibiting a field-induced slow magnetic relaxation behavior typical of single-ion magnets (SIMs). The hydrogen-bond-mediated self-assembly of this new bifunctional dysprosium(III) SIM in the solid state provides a unique example of 2D hydrogen bonded polymer with a herringbone net topology.
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