Journal
INORGANIC CHEMISTRY
Volume 52, Issue 10, Pages 5645-5647Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic400607w
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Funding
- Basic Science Research Program through the National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2011-0027419, 2012R1A1A2004333]
- Pohang Accelerator Laboratory [2012-3rd-2D-009]
- National Research Foundation of Korea [2009-0087194, 2013-PAL, 2012R1A1A2004333] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A heterometallic metal-organic framework incorporating Zn2+ and Ti4+ is successfully synthesized. The unique coordination mode of each metal ion to 2-oxido-1,4-benzenedicarboxylate leads to Zn6Ti2 building blocks, which extend to form a double-walled primitive cubic net. This material possesses a permanent porosity and long-term stability.
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