Journal
INORGANIC CHEMISTRY
Volume 52, Issue 19, Pages 10732-10734Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic4018757
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Funding
- NSFC [21001115, 21271117]
- Shandong Natural Science Fund for Distinguished Young Scholars [JQ201003]
- Fundamental Research Funds for the Central Universities [13CX05010A, 13CX02006A]
- [NCET-11-0309]
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A new type of 3D strongly self-catenated metal-organic framework (SDU-9) has been constructed from [Cu-2(COO)(4)] paddlewheel secondary building units and a tripodal carboxylate linker. SDU-9 ([Cu-6(H2O)(6)L-4]center dot 24H(2)O, where [H3L = 4,4',4 ''-(hydroxysilanetriyl)tris(triphenyl-4-carboxylic acid), represents a rare example of a highly symmetrical coordination network and extremely tight self-catenation. To the best of our knowledge, SDU-9 has the highest topological density among all known 3,4-coordinated nets.
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