Journal
INORGANIC CHEMISTRY
Volume 52, Issue 4, Pages 1667-1669Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic301707h
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Funding
- National Natural Science Foundation of China [21071087, 91122012]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars
- Outstanding Dissertation Growth Fundation of Ningbo University
- K. C. Wong MagnaFund in Ningbo University
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A doubly interpenetrated metal-organic framework, [Zn-3(TATB)(2)(H2O)(2)](n) (2), with chiral (10,3)-a topology, has been synthesized from an achiral, trigonal-planar ligand, 4,4',4 ''-s-triazine-2,4,6-triyltribenzoate (TATB). The large chiral channels in 2 act as scaffolds for the inclusion of N,N-dimethylaniline (DMA) molecules by donor-acceptor interactions. The resulting host-guest composite, DMA@2, shows desirably intense luminescence, which originated from photoinduced charge-transfer interactions in excited states.
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