Journal
INORGANIC CHEMISTRY
Volume 52, Issue 7, Pages 3772-3779Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic302364d
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Funding
- New Energy and Industrial Development Organization (NEDO), Japan
- MEXT, Japan [2107]
- Grants-in-Aid for Scientific Research [22350057, 24655115, 24108743] Funding Source: KAKEN
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Coordination polymers have significant potential for new functionality paradigms due to the intrinsic tunability of both their electronic and structural properties. In particular, octacyanometallate-bridged coordination polymers have the extended structural and magnetic diversity to achieve novel functionalities. We demonstrate that [Mn(H2O)][Mn(HCOO)(2/3)(H2O)(2/3)](3/4)[Mo(CN)(8)]center dot H2O can exhibit electrochemical alkali-ion insertion/extraction with high durability. The high durability is explained by the small lattice change of less than 1% during the reaction, as evidenced by ex situ X-ray diffraction analysis. The ex situ X-ray absorption spectroscopy revealed reversible redox of the octacyanometallate. Furthermore, the solid state redox of the paramagnetic [Mo-V(CN)(8)](3-)/diamagnetic[Mo-IV(CN)(8)](4-) couple realizes magnetic switching.
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