Journal
INORGANIC CHEMISTRY
Volume 52, Issue 5, Pages 2265-2267Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ic302375z
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Funding
- Basic Science Research Program through the National Research Foundation of Korea
- Ministry of Education, Science and Technology [2010-0003672]
- National Research Foundation of Korea [2010-0003672] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Coordination polymer networks, i.e., [Zn-(tpmd)(H2O)](NO3)(2)center dot 7H(2)O (1) and [Cd(tpmd)(H2O)(2)](NO3)(2)center dot 4H(2)O center dot 4CH(3)OH (2), were assembled from M-II(NO3)(2) hydrates (M = Zn, Cd) and N,N,N',N'-tetrakis(pyridin-4-yl)methanediamine (tpmd) in CH3OH and characterized. 1 and 2 feature three-dimensional networks formed by coordination of the metal ions to the tpmd ligands. 1 exhibits a strong blue emission at similar to 397 nm, while 2 shows strong emission at similar to 361 nm. 1 is a more efficient catalyst for the transesterification of various esters than 2.
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